Lecture #31 | ||
Text: Chapter 19, Sections 1, 3, 4. |
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Lecture Outline |
Molecular Basis of Solubility
(continued) Oxidation Numbers Transition metals |
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Vitamin A shown here is essentially a nonpolar molecule. It is very polarizable because of its "size" (and also because pi electrons are very polarizable, a detail we haven't worried about and will not). Consequently, it is not very soluble in water but quite soluble in a nonpolar solvent such as "fat" (which is mostly hydrocarbon-like in nature). | ![]() |
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In contrast to Vitamin A, you can see here from the structure of Vitamin C that extensive hydrogen bonding with solvent water molecules should be possible, explaining why it is a water soluble vitamin. | ![]() |
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Acetic acid, as a small, polar molecule capable of hydrogen bonding with water is very soluble in water. You might reasonably expect it to be insolube in nonpolar solvents. However, a subtle phenomenon causes acetic acid to be soluble in nonpolar solvents as well. See below. | ![]() |
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Our rules for oxidation numbers. These are "heirarchical", that is, each rule's rank determines their importance relative to other rules. They are not the same as in Table 4.3. | ||
Oxidation number rules continued | ||
Oxidation number rules continued |